Yeah, I've noticed this with both water and stronger solvents as well. I think that it could be due to differing polarities of some of the compounds (as in, it wouldn't be
just H20 on top, but H20 and soluble carbohydrates
in the H20). Like yepimonfire said, it's a suspension so depending on the solubility/polarity and sheer weight, you will end up getting that sort of separation.
If only it was as easy as pipetting off the top layer with pure kavalactones...well